Document Type
Article
Abstract
Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism.
Publication Date
August 2014
Publication Title
Beilstein Journal of Organic Chemistry
Volume
10
Issue
1
First Page
1933
Last Page
1941
DOI
10.3762/bjoc.10.201
Recommended Citation
Malla, Raj; Ridenour, Jeremy; and Spilling, Christopher, "Relay Cross Metathesis Reactions of Vinylphosphonates" (2014). Chemistry & Biochemistry Faculty Works. 51.
DOI: https://doi.org/10.3762/bjoc.10.201
Available at:
https://irl.umsl.edu/chemistry-faculty/51