Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism.
Beilstein Journal of Organic Chemistry
Malla, Raj; Ridenour, Jeremy; and Spilling, Christopher, "Relay Cross Metathesis Reactions of Vinylphosphonates" (2014). Chemistry & Biochemistry Faculty Works. 51.
Available at: https://irl.umsl.edu/chemistry-faculty/51