Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)

Authors

Nigam Rath, University of Missouri–St. Louis
Meghan Stouffer, University of Washington
Matthew Janssen, University of Washington
John Bleeke, University of Washington

Document Type

Article

Abstract

The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half mol­ecules of the two closely related FeII complexes lying on mirror planes and a tetra­hydro­furan solvent mol­ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex mol­ecules, a distorted octa­hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H...O inter­actions are observed in the crystal structure.

Publication Date

April 2011

Publication Title

Acta Crystallographica Section E-structure Reports Online

Volume

67

Issue

4

First Page

m462

Last Page

sup-10

DOI

10.1107/S1600536811009305

Recommended Citation

Rath, Nigam; Stouffer, Meghan; Janssen, Matthew; and Bleeke, John, "Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)" (2011). Chemistry & Biochemistry Faculty Works. 21.
DOI: https://doi.org/10.1107/S1600536811009305
Available at: https://irl.umsl.edu/chemistry-faculty/21