Dioxidobis(2-Oxo-1,2-Dihydropyridin-3-Olato)­Molybdenum(VI)

Authors

Manoj Trivedi, Banaras Hindu University
Daya Pandey, Banaras Hindu University
Nigam Rath, University of Missouri–St. Louis

Document Type

Article

Abstract

In the title compound, [Mo(C5H4NO2)2O2], the MoVI atom exhibits a distorted octa­hedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains inter­molecular N-H...O hydrogen bonds, C-H...O contacts and face-to-face [pi]-[pi] stacking inter­actions with an inter­planar separation of 3.25 (1) Å.

Publication Date

April 2008

Publication Title

Acta Crystallographica Section E-structure Reports Online

Volume

64

Issue

4

First Page

m595

Last Page

sup-8

DOI

10.1107/S1600536808007782

Recommended Citation

Trivedi, Manoj; Pandey, Daya; and Rath, Nigam, "Dioxidobis(2-Oxo-1,2-Dihydropyridin-3-Olato)­Molybdenum(VI)" (2008). Chemistry & Biochemistry Faculty Works. 56.
DOI: https://doi.org/10.1107/S1600536808007782
Available at: https://irl.umsl.edu/chemistry-faculty/56