Document Type
Article
Abstract
The O-allylphenyl (AP) anomeric moiety was investigated as a new leaving group that can be activated for chemical glycosylation under a variety of conditions, through both direct and remote pathways. Differentiation between the two activation pathways was achieved in a mechanistic study. The orthogonal-type activation of the AP moiety along with common thioglycosides allows for the execution of efficient oligosaccharide assembly.
Publication Date
April 2012
Publication Title
Beilstein Journal of Organic Chemistry
Volume
8
Issue
1
First Page
597
Last Page
605
DOI
10.3762/bjoc.8.66
Recommended Citation
Premathilake, Hemali and Demchenko, Alexei, "2-Allylphenyl Glycosides as Complementary Building Blocks for Oligosaccharide and Glycoconjugate Synthesis" (2012). Chemistry & Biochemistry Faculty Works. 36.
DOI: https://doi.org/10.3762/bjoc.8.66
Available at:
https://irl.umsl.edu/chemistry-faculty/36
